Abstract
Results of lattice dynamics, or atomic motions in a solid, explain many of the thermodynamic properties of solids. Inelastic neutron scattering conveniently explores the atomic motions, quantized as phonons. Of particular interest are materials that undergo structural phase transitions. The soft mode theory has been successful in relating anomalous phonon behavior to structural changes in solids. One such example is the ferromagnetic shape memory alloy, Ni2MnGa, which undergoes a sequence of phase transitions leading to a magnetic, incommensurate modulated, tetragonal phase as the ground state. The experiments, coupled with first principles calculations, provide evidence that strong electron–phonon coupling is the driving mechanism of the phase transformation.
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