Lattice distortion-driven band gap engineering and enhanced electrocatalytic activity of Mn-substituted nanostructured SrTiO3 materials: A comprehensive investigation

Abstract

The lattice distortion and electrocatalytic activity are investigated by the mono-substituent of Mn with different concentrations to generate localized states in the electronic structure of SrTiO3. The sol-gel approach has been employed to fabricate SrTiO3 and SrTi1-xMnxO3 nanostructures (NSs). The structural analysis indicates Mn incorporation into Ti sites of SrTiO3, which shifts the lattice towards a higher diffraction angle with a single-phase cubic structure. The optical absorption spectra exhibit a decrease in band gap from 3.27 to 1.89 eV and reveal the shift in band edge positions towards the visible region. XPS analysis is carried out to confirm the formation of oxygen vacancies and valence band edge position. For SrTi0.88Mn0.12O3, OER and HER have the overpotential of 445 and 157 mV at a current density of 100 and 10 mA cm−2. Hence, the substitution of Mn (x = 0.12) into SrTiO3 lattice results in lattice distortion that enhances the electrochemical performance compared to SrTiO3. The current work manifestly established the optimal Mn composition (x = 0.12) in SrTiO3 lattice as desirable materials with defective valence states for required electrocatalytic redox potential as well as the acceleration of charge transfer kinetics towards water splitting applications.