Abstract

Gas/liquid two-phase transport is the key fundamental scientific issue in the proton exchange membrane (PEM) water electrolysis cell, which has important effects on the overall performance of water electrolysis and microstructure optimization. In this study, a combination of the lattice Boltzmann two-phase model and the QSGS numerical method was used to numerically model the porous diffusion layer and the micro-channel structure, and investigate the effects of porosity and wettability properties on the gas/liquid two-phase transport process. Simulation results show that the value of porosity will obviously affect the association and distribution pattern of solid particles inside the porous diffusion layer, and the reduction of porosity will cause the association part of solid particles to be narrower and longer, resulting in complex and variable pore channels. Some closed pore channels will appear inside the diffusion layer, which is not conducive to the smooth transmission of gas bubbles. In addition, the increase of contact angle will enhance the interaction force between the bubble and the solid wall, making it difficult for the bubble to fall off from the solid surface. Moreover, the increased interaction force will slow down the sliding speed of gas bubbles, which will result in the fusion of more gas bubbles and increase the risk of blocking the flow micro-channel. This study has initially grasped the mechanisms of micro/meso scale gas bubble transport in the PEM water electrolysis cell, which will provide theoretical basis for the optimized development of high-performance water electrolysis system for hydrogen production.

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