Abstract

The Rum Layered Suite, NW Scotland, hosts Cr-spinel seams at the bases of peridotite–troctolite macro-rhythmic units in the eastern portion of the intrusion. Here, we present detailed field observations together with microstructural and mineral chemical analyses for the Unit 7–8 Cr-spinel seam and associated cumulates in the Eastern Layered Intrusion. Detailed mapping and sampling reveal significant lateral variations in the structural characteristics and mineral compositions of the Unit 7–8 boundary zone rocks. Although the Cr-spinel seam is laterally continuous over ~ 3 km, it is absent towards the centre and the margins of the intrusion. The compositional characteristics of Cr-spinel and plagioclase vary systematically along strike, exhibiting a chemical evolution towards more differentiated compositions with increasing distance from the main feeder conduit of the Rum intrusion; the Long Loch Fault. On the basis of our combined datasets, we propose that the upper part of the troctolite, the anorthosite layer underlying the Cr-spinel seam and the seam itself formed during a multi-stage magma replenishment event. The stages can be summarised as follows: (1) peridotite schlieren and anorthosite autoliths formed following melt infiltration and cumulate assimilation in the crystal mush of the Unit 7 troctolite. (2) The anorthosite layer then formed from the Unit 7 troctolite crystal mush by thermal erosion and dissolution due to infiltrating magma. (3) Subsequent dissolution of the anorthosite layer by new replenishing magma led to peritectic in situ crystallisation of the Unit 7–8 Cr-spinel seam, with (4) continued magma input eventually producing the overlying Unit 8 peridotite. In the central part of the Rum Layered Suite, the aforementioned assimilation of the troctolitic footwall formed the anorthosite layer. However, the absence of anorthosite in close proximity to the Long Loch Fault can be explained by enhanced thermochemical erosion close to the feeder zone, and its absence close to the margins of the intrusion, at maximum distance from the Long Loch Fault, may be due to cooling of the magma and loss of erosion potential. In line with other recent studies on PGE-bearing chromitites in layered intrusions, we highlight the importance of multi-stage intrusive magma replenishment to the formation of spatially coupled anorthosite and Cr-spinel seams, as well as the lateral mineral chemical variations observed in the Unit 7–8 boundary zone cumulates.

Highlights

  • The formation of Cr-spinel seams in layered intrusions remains a controversial phenomenon in igneous petrology (Irvine 1975, 1977; Namur et al 2015; Wager and Brown 1967)

  • The most platinum-group elements (PGE)-rich Rum Crspinel seams occur at the peridotitic bases of macro-rhythmic layers in the Eastern Layered Intrusion (ELI; Fig. 1), which has been taken by previous workers as evidence that they likely formed during some significant replenishment of the magma chamber by primitive magma (Dunham and Wadsworth 1978; O’Driscoll et al 2009a, 2010; Power et al 2000)

  • We investigated the Unit 7–8 Cr-spinel seam and associated hanging wall and footwall lithologies over the lateral extent of the ELI by carrying out field documentation as well as microstructural and mineral chemistry analyses, revealing significant lateral variations in the macro-tomicrostructural and mineral chemical character of the package of rocks

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Summary

Introduction

The formation of Cr-spinel seams in layered intrusions remains a controversial phenomenon in igneous petrology (Irvine 1975, 1977; Namur et al 2015; Wager and Brown 1967). The Rum Cr-spinel seams have been the objects of careful petrological study for decades (Brown 1956; Emeleus 1994, 1997; Harker 1908; Henderson and Suddaby 1971; Hepworth et al 2017; O’Driscoll et al 2009a, 2009b, 2010; Volker and Upton 1990; Young 1984) This is due in part to the fact that some of the seams exhibit significant, albeit sub-economic, enrichment in the PGE (Butcher et al 1999; O’Driscoll et al 2009a; Power et al 2003). Establishing the relationships between the Cr-spinel seams and their host rocks, and whether these vary along strike, could reveal valuable information on the nature and extent of interaction of the replenishing magma with its footwall cumulates leading to precious metal enrichment in the Rum intrusion

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