Late Paleozoic adakitic magmatism in the Zogdor Cu occurrences, southern Mongolia, and their tectonic implications: New SHRIMP zircon age dating, Lu-Hf isotope systematics and geochemical constraints

Abstract

The Zogdor Cu occurrences are located in the Gurvansayhan island arc terrane of southern Mongolia, which corresponds to the southern part of the Central Asian Orogenic Belt (CAOB). The major porphyry type copper–gold (molybdenum) mineralized belt including Oyu Tolgoi, Tsagaan Suvarga, Shuteen, and Kharmagtai deposits are located in this terrane and were known to have formed during 372–324 Ma. The Zogdor Cu occurrences are found within this porphyry Cu-Au mineralized belt and are limitedly distributed in granitoids including granodiorite and monzogranite. In this study, we present new SHRIMP zircon U-Pb geochronology, LA-MC-ICPMS zircon Lu-Hf isotopes, and geochemical data for the granitoids in the Zogdor Cu occurrences and provide a new tectonic model including igneous activities and Cu mineralization in southern Mongolia. The emplacement ages of granodiorite and monzogranite are 329.1–326.4 Ma, and 329.9–326.1 Ma, respectively. All zircons have positive εHf values corresponding to two-stage model ages (T2DM) ranging from 581 to 331 Ma, possibly demonstrating that late Neoproterozoic to middle Carboniferous juvenile continental crust growth was derived from a depleted mantle source. Both granitoids are characterized by high Al2O3 and Sr, and low Y and Yb contents, as well as high Sr/Y and (La/Yb)N ratios, which are typical geochemical characteristics of adakites. The trace elements are characterized by an enrichment in the large ion lithophile elements (e.g., Cs, Rb, Ba, and Sr) and a depletion in the high field strength elements (e.g., Nb, P, and Ti), indicating that these granitoids intruded in subduction tectonic settings. In conclusion with data from previous studies, the intermittent igneous activities during the Cambrian to Ordovician (519–482 Ma), middle Devonian (374–363 Ma), middle to late Carboniferous (353–304 Ma), and early Permian (298–286 Ma) took place in the southern Mongolia and porphyry copper mineralizations seem to be closely related the middle Devonian and middle Carboniferous adakitic or adakite-like magmatism. The Lu-Hf isotopic results for these associated granitoids including previous Rb-Sr and Sm-Nd isotopic studies imply that the Neoproterozoic to middle Carboniferous juvenile continental growth derived from a depleted mantle source. The middle Devonian and middle Carboniferous magmatic activities triggered by the subduction of the Paleo-Asian Oceanic plate and formed the porphyry copper deposits in the southern Mongolia.