Abstract
In recent times, the use of Chemical Warfare (CW) agents against civilian and military by terrorists and rogue countries are recurrent. The examples of such attacks are available in open literature. They are highly dangerous due to their acute toxicity nature. They tend to stimulate and paralyze nerve system of the body and cause other toxic side effects. Once these toxic chemicals are released into the atmosphere, timely detection and identification of the same at standoff distances will help the defensive forces to take proper counter measures. Detection techniques such as ion mobility spectrometry, infrared spectrometry, Raman spectrometry, FTIR, LIDAR, etc. have been used widely. Among all these techniques, Raman spectroscopy techniques and LIDAR (LIght Detection and Ranging) is the only active remote detection method that can detect and discriminate the chemical agents at standoff distances. Infrared DIAL (Differential Absorption Lidar) is a versatile technique for remote detection of various chemicals. DIAL technique can provide spatially resolved measurements of these agents with sufficient sensitivity (at few ppm levels) at ranges of several kilometers by exploiting the concept such as scattering and absorption from the atmosphere. The main objective of this review paper is to bring out the details of highly potential chemical warfare agents, their properties and laser based remote detection sensors. LIDAR technique is emphasized in more detail because of their long range detection capability, sensitivity and selectivity. An overview of existing R&D based and commercial systems is also discussed.
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