Abstract
The influence of laser surface treatment on the isothermal oxidation of Ni-10%Cr and Ni-15%Cr at 1025°C in oxygen at 1 atm pressure has been studied. Particular emphasis has been placed on the progressive establishment of a Cr2O3 healing layer, which is facilitated by rapid-diffusion paths for chromium to the surface from the bulk alloy. For nonlaser treated alloys, such paths are alloy grain boundaries. A partial Cr2O3 layer forms initially in localized sites at, and immediately adjacent to, these boundaries and progresses into the alloy grains in a stepwise manner following lateral diffusion of chromium from the grain boundaries, thereby developing a contoured configuration. For Ni-15%Cr, there is sufficient chromium in the bulk alloy grains to sustain the eventual development of a self-healing layer parallel to the surface. For Ni-10%Cr, this is not the case and complete development of the healing layer results entirely from the stepwise progression from the grain boundaries. Establishment of the healing layer on laser-glazed surfaces is facilitated by additional rapid-diffusion paths, particularly retained alloy grain boundaries, retained alloy twins, a laser-induced microstructure and solidification artifacts (such as ripples). The relative importance of these features is discussed in relation to the oxidation behavior.
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