Abstract
Laser induced fluorescence spectra, using a single frequency ring dye laser, have shown hyperfine structure in transitions from the A[14.79]8.5 state of HoS to three low-lying electronic states, X18.5, X27.5 and W17.5. Analysis of the hyperfine structure yielded magnetic hyperfine parameters, h(X1)=0.3298(27)cm−1, h(X2)=0.1124(29)cm−1, h(W1)=0.275(5)cm−1 and h(A)=0.2314(25)cm−1. The three low lying states originate from the ground Ho2+{4f10(5I8)6s}S2− configuration and the hyperfine parameters were used to determine the free Ho2+ ion quantum numbers appropriate to each state as well as the approximate relative contributions of the 4f and 6s electrons to the overall hyperfine energy. Calculation of the ground state magnetic hyperfine parameter h(X18.5) from atomic hyperfine parameters was found to be consistent with the observed values.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.