Abstract
Lasers and laser spectroscopic techniques have been extensively used in several applications since their advent, and the subject has been reviewed extensively in the last several decades. This review is focused on three areas of laser spectroscopic applications in atmospheric and environmental sensing; namely laser-induced fluorescence (LIF), cavity ring-down spectroscopy (CRDS), and photoluminescence (PL) techniques used in the detection of solids, liquids, aerosols, trace gases, and volatile organic compounds (VOCs).
Highlights
There are numerous traditional optical, gas chromatographic and mass spectrometric methods that have served extremely well in the detection of atmospheric and environmental trace gases, solid, and liquid compounds
This review is focused on three areas of laser spectroscopic applications in atmospheric and environmental sensing; namely laser-induced fluorescence (LIF), cavity ring-down spectroscopy (CRDS), and photoluminescence (PL) techniques used in the detection of solids, liquids, aerosols, trace gases, and volatile organic compounds (VOCs)
This development leads to Laser Induced Breakdown Spectroscopy (LIBS), where a single laser pulse forms a plasma, on a solid surface or within a gas or liquid, that results in volatilization and emission from atomic species
Summary
The use of coordination complexes for sensing applications of VOCs is currently attracting a great deal of attention as an alternative approach to polymeric materials. The use of transition metal complexes as optical sensors for VOC detections has increased exponentially. The review by Keefe et al discusses the earlier developments (1994 to early 1999) of luminescence-based chemical sensing as they relate to the coordination chemistry of metals [277]. In the first part of this section, recent investigations of transition metal complexes that are used and/or have the potential for PL sensing are covered. This initial section includes transition metal complexes comprising of gold, mixed gold-silver, mixed gold-thallium, copper, and platinum-based systems, which have all proven to exhibit intriguing vapoluminescent properties. The review will cover literature reported since the year 2000, with a few exceptions of earlier exemplary works
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