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Abstract
AbstractThe Raman spectra of [Ag(CO)2]+ and [Cu(CO)4]+ in fluorosulphonic acid at—50°C have been investigated in the CO stretching region. These data, together with previously reported infrared results, favour D∞h symmetry for the Ag(I) species and Td symmetry for the Cu(I) species. These structures are in accord with those predicted for the complexes using the valence shell electron pair repulsion (VSEPR) theory.
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