Abstract
The vibrational relaxation and noncoincidence effect in liquid cyclohexanone have been studied and explained in terms of molecular attraction parameters and van der Waals interactions. The line broadening of the isotropic component of the CO stretching mode of cyclohexanone in different solvents is explained on the basis of dispersion forces. The parameter involving viscosity, density and refractive index has been correlated with the vibrational relaxation rate.
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