Laser pulse shaping for optimal control of multiphoton dissociation in a diatomic molecule using genetic algorithm optimization

Abstract

We have applied genetic algorithm optimization for the design of laser pulses to control dissociation process in the ground electronic state of HF molecule, within the mathematical framework of optimal control theory. In order to design the experimentally feasible laser fields, we coded the small set of selected field parameters in the GA parameter space. Two types of pulses, one with fixed frequency components and the other having non-deterministic components have been designed. Optimized laser field obtained using this approach, possesses simple time and frequency structures. We show that the fields having non-deterministic frequency components lead to greater dissociation probability compared to the ones having deterministic frequency components.