Laser initiated reactions in N2O clusters studied by time-sliced ion velocity imaging technique

Abstract

Laser initiated reactions in N2O clusters were studied by a time-sliced velocity imaging technique. The N2O clusters, (N2O)n, generated by supersonic expansion were irradiated by an ultraviolet laser around 204 nm to convert reactant pairs, O((1)D2)-(N2O)n-1. The NO molecules formed from these reactant pairs were ionized by the same laser pulse and their velocity distribution was determined by the time-sliced velocity imaging technique. At low nozzle pressure, lower than 1.5 atm, the speed distribution in the frame moving with the clusters consists of two components. These components were ascribed to the products appeared in the backward and forward directions in the center-of-mass frame, respectively. The former consists of the vibrational ground state and the latter consists of highly vibrational excited states. At higher nozzle pressure, a single broad speed distribution became dominant for the product NO. The pressure and laser power dependences suggested that this component is attributed to the product formed in the clusters larger than dimer, (N2O)n (n ≥ 3).