Laser-induced formation of Au/Pt nanorods with peroxidase mimicking and SERS enhancement properties for application to the colorimetric determination of H2O2.

Abstract

Platinum nanoparticles (PtNPs)were uniformly grown on the surface of gold nanorods (AuNRs) by a laser irradiation procedure. Transmission electron microscopy confirmed that the PtNPs are uniformly grown on the surface of theAuNRs. The formation of PtNPs on the AuNRs leads to a red-shift of the absorption maximum from 734nm to 766nm. In addition, the efficiency of surface enhanced Raman scattering (SERS) is increased, but the photothermal conversion efficiency is decreased compared to pure AuNRs. The result indicates that electron transfer occurs between gold and platinum. The peroxidase mimicking effect of PtNPs, AuNRs and Au/Pt NRs by catalyzing the oxidation of colorless 3,3',5,5'-tetramethylbenzidine (TMB) to blue oxidized 3,3',5,5'-tetramethylbenzidine (oxTMB; a quinone) in the presence of H2O2. The catalytic activity of Au/Pt NRs is higher than that of sole AuNRs or PtNPs by factors of4.2 and 2.1, respectively. Thus, Au/Pt NRs have been used for the detection of peroxide and the limit of detection is 0.04μM. This work provides an approach to integrate the peroxidase mimicking effect with SERS enhancement for potential application in detection. Graphical abstract A schematic diagram for the laser-induced growth of Au/Pt NRs and the colorimetric determination of hydrogen peroxide concentration with their peroxidase mimicking properties. The limit of detection is 0.04μM based on the use ofAu/Pt NRs as acatalyst.