Abstract
An iterative band contour simulation strategy has been extended to the analysis of partially resolved rovibronic bands in the laser-induced fluorescence (LIF) spectra of complexes of jet-cooled, substituted aromatic amines (4-aminobenzonitrile, ethyl 4-aminobenzoate, methyl 4-aminobenzoate, 4-pyrrolidinobenzonitrile, ethyl 4-pyrrolidinobenzoate and methyl 4-pyrrolidinobenzoate) with both polar and non-polar solvents. The pattern which emerges on complexation with non-polar solvents is of a high degree of site selectivity. With polar solvents several distinct conformers are observed, with different solvent shifts, for the same complex stoichiometry.
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