Abstract
We have generated the p-chlorobenzyl radical in supersonic free expansion, and measured the laser-induced fluorescence (LIF) excitation spectra and LIF dispersed spectra from single vibronic levels (SVL). Based on an analysis of the dispersed spectra, we find the two band origins, spaced only 94 cm −1 apart, of the D 1 1 2A 2− and D 2 2 2B 1−D 0 1 2B 1 transitions in the excitation spectrum. We also observe interstate level mixing between the 6b and 12 vibronic levels of the D 2 and D 1 states, respectively, in the excitation spectrum, and the vibronic coupling is analyzed using a simple model within the Born-Oppenheimer (B-O) approximation.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
