Abstract

Abstract : A coated surface of a crystal is irradiated by intense infrared light. The optically active atomic bonds absorb photons from the laser field, and the subsequent spontaneous decay goes together with emissions of phonons into the crystal. This photon phonon conversion results in an energy flux into the crystal. An equation for this flux is derived from the master equation for the level populations of the dressed atomic states. The saturation limit is discussed, and the general theory is illustrated with two examples. Furthermore, it is outlined with qualitative arguments that quantum yield of photodesorption is not sensitive to the laser power. Keywords: Laser heating; Transparent crystal; VIA Adsorbed atoms; Photon phonon conversion; Master equation; photodesorption.

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