Laser co-photolytic approach to copper(I) bromide/polymer nanosol and nanocomposite

Josef Pola,Akihiko Ouchi,Petr Bezdička,Jaroslav Boháček,Jan Šubrt

doi:10.1016/j.jphotochem.2007.03.008

Laser co-photolytic approach to copper(I) bromide/polymer nanosol and nanocomposite

Josef Pola, Akihiko Ouchi + Show 3 more

https://doi.org/10.1016/j.jphotochem.2007.03.008

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Journal: Journal of photochemistry and photobiology. A, Chemistry	Publication Date: Mar 12, 2007
Citations: 2

Affiliation: Czech Academy of Sciences, Institute of Chemical Process Fundamentals, National Institute of Advanced Industrial Science and Technology, Czech Academy of Sciences, Czech Academy of Sciences, Institute of Inorganic Chemistry

#Brominating Reagent #CuBr Nanoparticles + Show 5 more

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Abstract

KrF laser co-photolysis of Cu(II) acetylacetonate and 1-bromoeicosane in 2-propanol results in the formation of CuBr/polymer colloidal solution aging of which results in sedimentation of CuBr/polymer nanocomposite. This clean process involves a reaction between two photo-products (nano-sized Cu and a brominating reagent) and photolytic formation of polymer. The CuBr nanoparticles embedded in a photo-produced polymer possess zinc blende-type cubic structure. The co-photolytic procedure represents a new approach to polymer-stabilized nano-inorganic compounds.

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