Abstract
AbstractNanostructured metal sulfide–amine hybrid materials have attracted attention because of their unique properties and versatility as precursors for functional inorganic nanomaterials. However, large‐scale synthesis of metal sulfide–amine hybrid nanomaterials is limited by hydrothermal and solvothermal preparative reaction conditions; consequently, incorporation of such materials into functional nanomaterials is hindered. An amine molecule‐assisted refluxing method was used to synthesize highly uniform zinc sulfide⋅(diethylenetriamine)0.5 (ZnS⋅(DETA)0.5) hybrid nanosheets and nanobelts in a large scale. The obtained ZnS⋅(DETA)0.5 hybrid nanomaterials can be used as efficient precursors to fabricate functional ZnS nanomaterials and carbon encapsulated sulfur (S@C) nanocomposite cathodes for Li–S batteries.
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