Large-Scale Preparation for Multicolor Stimulus-Responsive Room-Temperature Phosphorescence Paper via Cellulose Heterogeneous Reaction.

Abstract

The large-scale preparation of sustainable room-temperature phosphorescence (RTP) materials, particularly those with stimulus-response properties, is attractive but remains challenging. This study develops a facile heterogeneous B─O covalent bonding strategy to anchor arylboronic acid chromophores to cellulose chains using pure water as a solvent, resulting in multicolor RTP cellulose. The rigid environment provided by the B─O covalent bonds and hydrogen bonds promotes the triplet population and suppresses quenching, leading to an excellent lifetime of 1.42 s for the target RTP cellulose. By increasing the degree of chromophore conjugation, the afterglow colors can be tuned from blue to green and then to red. Motivated by this finding, a papermaking production line is built to convert paper pulp reacted with an arylboronic acid additive into multicolor RTP paper on a large scale. Furthermore, the RTP paper is sensitive to water because of the destruction of hydrogen bonds, and the stimuli-response can be repeated in response to water/heat stimuli. The RTP paper can be folded into 3D afterglow origami handicrafts and anti-counterfeiting packing boxes or used for stimulus-responsive information encryption. This success paves the way for the development of large-scale, eco-friendly, and practical stimuli-responsive RTP materials.