Large-scale micro-aerobic digestion studies at municipal water resource recovery facilities for process-integrated biogas desulfurization

Abstract

Biogas generated from anaerobic digestion processes typically requires gas conditioning including hydrogen sulfide removal before it is used on-site to generate electricity and heat or before upgrading to biomethane for gas pipeline distribution or vehicle fuel. Experiments of process-integrated micro-aeration in three different large-scale sludge digesters (effective volume 2450 m3, 3250 m3 and 3300 m3) were undertaken at municipal wastewater treatment plants and compared with large-scale applications reported in literature. This work discusses critical process parameters, advantages, and potential limitations of micro-aerobic digestion in comparison with other commonly used biogas desulfurization methods. It shows that high H2S reduction in the biogas can be obtained and that the H2S reduction is dependent not only on the air injection rate and location, but also on the digestion activity identified by the volumetric biogas production. Reliability testing of typical micro-aerobic upset scenarios and long-term micro-aerobic digester operation as part of this study provided deeper insights in the MA process that could also provide valuable input to what operational, maintenance and safety measures should be considered when applying micro-aeration in large-scale digesters. The large-scale micro-aerobic digestion trials demonstrated that the hydrogen sulfide concentration in the biogas can be controlled using minimal plant upgrades, contributing to the sustainability and economic efficiency of the energy recovery process of waste sludge digestion at water resource recovery facilities.