Abstract
The magnetic and magnetocaloric effect (MCE) of Mg or Cu-doped Ba0.5Sr1.5Zn2Fe12O22 hexaferrites synthesized by the sol-gel method are investigated. The Ba0.5Sr1.5Zn2Fe12O22 shows a sharp paramagnetic to ferrimagnetic phase transition and a large conventional MCE at around room temperature. By the partial substitution of Zn with Mg or Cu, the magnetic transition temperature as well as the maximum MCE temperature can be tuned in the range of 300 and 375K while keeping the maximum MCE nearly unchanged, which are beneficial characteristics for their application as near room-temperature magnetic refrigerants. For Ba0.5Sr1.5Zn2Fe12O22, it is found that the maximum values of magnetic entropy change –ΔSM and relative cooling power (RCP) are 1.27J/kg K and 124J/kg for ΔH=4.4T, respectively. Given its advantages, such as large RCP, suitable working temperature, low-cost raw materials, easy to synthesize, and environment-friendly, the Ba0.5Sr1.5Zn2Fe12O22 related hexaferrites may be potential candidates for room-temperature magnetic refrigeration.
Sign-in/Register to access full text options 
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
