Abstract

Magnetic materials with reversible magnetocaloric effect across their respective first-order magneto-structural transitions (MST) have vital significance for further advancement towards the ultimate goal of practical magnetic cooling applications. In this present study, the reversibility of the MST is investigated by analyzing the isofield curves under different minor and major thermal hysteresis loops and the isothermal curves under different magnetic field cycles. The reversibility of the magnetocaloric effect (MCE) depends upon the width of the nucleation energy barrier existing across the MST. Minor hysteresis loops are found to be minimizing the energy loss by preventing the nucleation of the martensite phase and can be easily returned to the austenite phase immediately while switching from cooling to heating. A large reversible isothermal magnetic entropy change ΔSM of −14.4 J kg−1 K−1 nearly at 322 K is observed for the (Mn0.45Fe0.55) (Ni0.6 Co0.4) Si alloy under a low magnetic field change of 3 T. The observed large reversible MCE, very low magnetic field-induced hysteresis loss, and large reversible RCeffe ∼ 155 J kg−1 will be beneficial for reducing the energy loss during several magnetic field cycles in practical cooling applications which makes this alloy promising for the development of efficient magnetic refrigerants.

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