Abstract
Uniquely, large-bipolarons' self-trapped holes occupy superoxygens, each comprising four oxygens circumscribed by four coppers in a CuO2 plane, formed as oxygens relax inward and coppers relax outward. Critically, concomitant oxygen-to-copper electron transfer eliminates copper spins. The d-symmetry of superoxygens' ground state molecular orbital tracks the superoxygens' predominant zero-point radial vibrations. These large bipolarons' distinctive charge transport, absorption, magnetism, local atomic vibrations, condensation into a liquid, and subsequent superconductivity are consistent with cuprate superconductors' long-established unusual properties.
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