Abstract
A cheap and green technology based on electro-erosion, performed at room conditions and scalable to large area (cm2) is demonstrated for structuring graphene and graphene oxide films on any substrate. This one-step technique based on electrical discharges produced by a direct current voltage source competes favorably with laser patterning. The threshold voltage for complete graphene elimination as determined by Raman mapping is around 20V. At low relative humidity conditions (30%) the transformation to graphene oxide is also detected for operating voltages above 40V, the oxidation being probably mediated by the residual adsorbed water at the surface. We also show the close correlation of atomic force microscopy (AFM) phase images with the modified graphene characteristics while AFM topographic images are dominated by extrinsic aspects. The use of a spring probe relaxes the requirement of precision for the tip-sample distance and sample flatness to around 10μm which is very convenient for large scale applications. Furthermore, this technique allows the formation of high quality nanographene, with size around 18nm, and graphene micro-ribbon lattices in a very fast way and very well defined edges, with dimensions down to 1μm width and mm length, very promising for terahertz graphene plasmonic applications.
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