Laponite Nanoparticle as a High Performance Rheological Modifier in Water-Based Drilling Fluids

Abstract

In this paper, we demonstrated an artificial nanoparticles, Laponite, as a high performance rheological modifier in water-based drilling fluids. We made a comparison between Laponite nanoparticle and bentonite as rheological modifier in polyanionic cellulose (PAC) solution and weitghted water-based drilling fluids. In viscosity-shear rate test, both Laponite and bentonite could translate 0.5 wt.% PAC solution from Newton fluids to yield-pseudoplastic fluid. However, 1 wt.% Laponite was better in improving the shear-thinning behavior compared with 4 wt.% bentonite. In the stress-shear rate test, the results were fit with Bingham model with a high R2, and 1 wt.% Laponite/0.5 wt.% PAC suspension had a yield point of 5.19 Pa, which was higher than that of 4 wt.% bentonite/0.5 wt.% PAC suspension (3.13 Pa). Similarly, 1 wt.% Laponite/0.5 wt.% PAC suspension maintained a G’ of 12 Pa in the oscillation frequency sweep test, whereas G’ of 4%bentonite/0.5%PAC suspension was nearly 5 Pa. Particularly, 0.5 wt.% PAC /Laponite suspensions could maintain higher gel structure, yield point and better shear-thinning behaviors after 120°C hot rolling. The TEM image revealed that nanoscaled Laponite could form a “star network” with PAC in water, which explained the good rheological properties of PAC/LAP mixed suspensions. Besides, in the weighted drilling fluids, 1 wt.% Laponite could maintained a much higher gel strength compared with 4 wt.% bentonite.As the unique rheological properties, Laponite nanoparticles can greatly enhance abilities of water-based drilling fluids in circulating cuttings and making the borehole clean.