Lanthanum hexaaluminate — novel thermal barrier coatings for gas turbine applications — materials and process development

Abstract

Lanthanum hexaaluminate (LHA) with a magnetoplumbite structure is a promising competitor to yttria partially stabilized zirconia (Y-PSZ) as a thermal barrier coating (TBC), since most zirconia coatings age significantly, including undesired densification at temperatures exceeding 1100 °C. The microstructure of calcined lanthanum hexaaluminate powders and thermally sprayed coatings show a platelet structure. The magnetoplumbite structure is characterized by the highly charged La 3+ cation located in an oxygen position in the hexagonal close-packed structure of oxygen ions. Ion diffusion is strongly suppressed vertical to the crystallographic c-axis, thus hindering sintering densification. In contrast to the oxygen ion conducting zirconia, lanthanum hexaaluminate permits operating temperatures above 1300 °C because of its thermal stability and electrically insulating properties. This study describes the optimization of powder preparation for thermal spraying by spray drying and the development of parameters for atmospheric plasma spraying (APS) in order to produce homogeneous crystalline coatings with controlled micro-porosity and residual stresses. The phases were characterized by X-ray diffraction (XRD).