Abstract
Two novel macrocycles, L 1 and L 2, containing a N 3O 4-donor set, have been synthesised, and their complexation potential towards Ln(III) ions have been investigated. The cyclocondensation reaction between 2,6-bis(2-formylphenoxymethyl)pyridine and 1,2-bis(2-aminophenoxy)butane in the absence of metal ions, yields the macrocycle L 1 as the main product. The diamine macrocycle L 2 is formed by reaction of the diamine and dicarbonyl precursors followed by an in situ reduction with NaBH 4. The interaction of lanthanide(III) ions with both ligands has been investigated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
