Lanthanide(III) (Eu, Gd, Tb, Dy) Complexes Derived from 4-(Pyridin-2-yl)methyleneamino-1,2,4-triazole: Crystal Structure, Magnetic Properties, and Photoluminescence.

Abstract

The reaction of lanthanide(III) nitrates with 4-(pyridin-2-yl)methyleneamino-1,2,4-triazole (L) was studied. The compounds [Ln(NO3 )3 (H2 O)3 ]⋅2 L, in which Ln=Eu (1), Gd (2), Tb (3), or Dy (4), obtained in a mixture of MeCN/EtOH have the same structure, as shown by XRD. In the crystals of these compounds, the mononuclear complex units [Ln(NO3 )3 (H2 O)3 ] are linked to L molecules through intermolecular hydrogen-bonding interactions to form a 2D polymeric supramolecular architecture. An investigation into the optical characteristics of the Eu3+ -, Tb3+ -, and Dy3+ -containing compounds (1, 3, and 4) showed that these complexes displayed metal-centered luminescence. According to magnetic measurements, compound 4 exhibits single-ion magnet behavior, with ΔEeff /kB =86 K in a field of 1500 Oe.