Abstract
At heory of orientational relaxation for the inertial rotational Brownian motion of a symmetric top molecule is developed using the Langevin equation rather than the Fokker–Planck equation. The infinite hierarchy of differentialrecurrence relations for the orientationa lc orrelation functions for the relaxation behaviour is derived by averaging the corresponding Euler–Langevin equations. The solution of this hierarchy is obtained using matrix continued fractions allowing the calculation of the correlation times and the spectra of the orientational correlation functions for typical values of the model parameters.
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