Abstract

Electric glue plays a key role in laminating top electrodes for organic and perovskite thin-film solar cells. However, there has been seldom reported for chemically reactive low–work function electrode yet. In this paper, polyethyleneimine (PEI) was developed as transparent top electrode adhesive, surface modifier for air-stable low–work function, and barrier to suppress the chemical corrosion of metal electrode in perovskite solar cells. The lamination was finished under room temperature with a pressure as low as 8 MPa, which is a very mild condition for device fabrication. The solar cells with transparent top electrode laminated for 10min had the best performances, in which the average value of PEI thickness between silver nanowires and the adjacent layer was found to play a key role in adjusting the performance of solar cells.

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