Laminar Flame Speed Experiments of Alternative Liquid Fuels

Abstract

Abstract New laminar flame speed experiments have been collected for multiple alternative liquid fuels. Understanding the combustion characteristics of these synthetic fuels is an important step in developing new chemical kinetics mechanisms that can be applied to real fuels. Included in this study are two synthetic Jet fuels: Syntroleum S-8 and Shell GTL. The precise composition of these fuels is known to change from sample to sample. Since these are low vapor pressure fuels, there are additional uncertainties in their introduction into gas-phase mixtures, leading to uncertainty in the mixture equivalence ratio. An in-situ laser absorption technique was implemented to verify the procedure for filling the vessel and to minimize and quantify the uncertainty in the experimental equivalence ratio. The diagnostic utilized a 3.39-μm HeNe laser in conjunction with Beer’s Law. The resulting spherically expanding flame experiments were conducted over a range of equivalence ratios from φ = 0.7 to φ = 1.5 at initial conditions of 1 atm and 403 K in the high-temperature, high-pressure constant-volume vessel at Texas A&M University. The experimental results show that both fuels have similar flame speeds with a peak value just under 60 cm/s. However, it is shown that when comparing the results from different data sets for these real fuels, equivalence ratio is not necessarily the best parameter to use. Fuel mole fraction may be a better parameter to use as it is independent of the average fuel molecule or fuel surrogate used to calculate equivalence ratio in these real fuel/air mixtures.