Laboratory studies of physico-chemical methods to break emulsions stabilized with surfactant-polymer cocktails

Abstract

Introduction. Oil field treatment often makes it necessary to combine different methods of well production treatment, taking into account the development regimes and parameters, produced and injected fluids, technical equipment and economic feasibility. The carried-out complex of laboratory tests is aimed at the creation and subsequent destruction of model systems with specified parameters. The list of the considered methods and the temperature regime of the tests are due to the physicochemical parameters and the field specifics. The purpose of this article is to search for an effective method for the primary treatment of well production after SP-flooding — a highly stable oil-water emulsion, additionally stabilized during pumping by means of an ESP. 
 
 Materials and methods. The laboratory tests helped to develop an optimal mode of creating an artificial emulsion based on oil from BS10-1 reservoir of the Kholmogorsk field in the Yamalo-Nenets Autonomous Okrug, and a surfactant-polymer cocktail, which simulates well production after SP-flooding. The research tested physicochemical methods of destroying oil-water emulsions, such as their dilution with formation fluids, thermal settling, gravitational separation by centrifugation at RPM = 4000–12000 rpm, introduction of demulsifiers, as well as a combined effect, including all of the above approaches. The tested methods were supplied with the calculated values of the oil phase final water-cut, which allowed us to evaluate the effectiveness of the applied approaches to the destruction of model systems. 
 
 Results. It has been found that not all of the applied approaches provide the extraction of the estimated amount of oil from emulsion systems with varying degrees of dilution by formation fluids. Satisfactory destruction of the emulsion was achieved after 10–20 min of centrifugation at T = 40 °C and RPM within 4000–8000 rpm. The traditional introduction of industrial demulsifiers into the studied systems without additional influences is ineffective. 
 
 Conclusion. The optimal level of water cut in the oil phase of ≤5% was achieved after diluting the emulsion with formation fluids, with a combined approach to the destruction of the original and diluted emulsion with formation fluids. In addition, the research showed that it is possible to re-use the extracted SP-composition when controlling its physicochemical parameters, taking into account the effect of the introduced additives.