Abstract
The asymmetric unit of the title compound, C5H12NO2S+·NO3−, is composed of two crystallographically independent methioninium cations related by pseudosymmetry (−x, 1 \over 5 + y, ½ − z) and two nitrate anions related by a pseudo-inversion centre at (0.50, 0.43, 0.25). In one of the residues, the straight side-chain conformation is gauche II–trans–gauche II, while in the other it is gauche II–trans–trans. In the crystal, the methioninium residues form N—H⋯O hydrogen-bonded molecular columns, which are interlinked by N—H⋯O and O—H⋯O hydrogen bonds involving the O atoms of the nitrate groups.
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