Abstract

Inner-shell ionization has many applications related to material analysis. However, full theoretical calculations in heavy multielectronic atoms are scarce. In this contribution, we assess proton and electron impact Li and Mi-subshell ionization cross-sections of heavy targets (72≤Z≤83) using two theoretical models. These calculations are based on the Distorted Plane Wave Born Approximation for electron impact and the shellwise local plasma approximation for the proton impact, combined with relativistic calculations of these deep subshells wave functions and binding energies. We analyze the L-shell ionization of W, Au, and Bi and the M-shell of Hf, Ta, W, Re, Os, Pt, Au, Pb, and Bi. Present values are compared with available experimental data from the literature, with disparate agreement. The convergence of proton and electron impact cross-sections at high-impact velocities is also discussed.

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