Abstract
K beta X-ray lines from partially M-shell-ionized ions of titanium through nickel which are produced in vacuum-spark plasmas have been observed systematically for the first time, using a high-resolution curved-crystal spectrometer. Each K beta line is clearly separated into its corresponding charge state. As a result, it is possible to measure the K beta-type transition energies of the M-shell-ionized ions. The transition energies accurately determined are compared with those calculated for iron ions, and the agreement is excellent except for ions having some additional 3d outer-shell electrons or 3s inner-shell vacancies. The square root of the K beta transition frequency is expressed as a linear function of the nuclear charge for isoelectronic sequences. The effective nuclear charges have been also determined for each K beta transition. The 3p electrons do not affect the effective nuclear charges. 10 references.
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