Abstract
Abstract The compound {[Pt(dapn)2][Pt(dapn)2Br2]}(Cu3Br5)2, which was prepared by oxidation of Pt(dapn)2Br2 with CuBr2, crystallizes in the orthorhombic space group Bmmb (D2h 17), a = 5.617(4) Å, b = 16.206(6) Å, c = 22.00(1) Å, Z = 2. The experimentally determined density is 3.22 g · cm-3 (calculated 3.40). The structure has been determined by Patterson and Fourier methods from single crystal diffractometer data and refined by least squares to R = 0.085 for 485 independent reflections. Crystals of the title compound contain halide-bridged copper and platinum chains.
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