Kratzer potential algebraic representation and matrix elements recurrence formulae

Abstract

Generalized recurrence relations for the calculation of multipole matrix elements for Kratzer potential wave functions are obtained operationally. These formulas have been determined by using a non-analytical procedure based on the algebraic representation of the Kratzer eigenfunctions along with the usual ladder properties and commutation relations. For that, the creation and annihilation operators are adequately derived by means of an alternative approach to the factorization method and the exact expressions for matrix elements are achieved with the aid of a relationship between the ladder operators associated with the bra and theket. The proposed algebraic approach as well as the formulas for the calculation of matrix elements thus derived are quite simple and direct when compared with other alternative expressions already obtained analytically or pseudo-algebraically by means of the hypervirial theorem commutator algebra.