Abstract

AbstractThe polarograms of the metal complexes of Ethylenediaminetetraacetic Acid and of 1,2‐Diaminocyclohexane‐tetraacetic Acid are described. In a mixture, containing the metal complex MYv−4 as well as the uncomplexed cation M+v, it is usually possible to determine the concentration of the latter with high accuracy with the aid of a polarograph. Such measurements have been used for the determination of the ratios of the formation constants of the complexes of two metals M and M′, and from these ratios the individual formation constants of 49 complexes have been obtained. The best values of the formation constants (20°, μ = 0,1) of metal complexes are tabulated.

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