Abstract
Complex Catalysis with Technetium Compounds. Hydroformylation with Technetiumcarbonyl CatalystsThe hydroformylation reaction of cyclohexene (1), propene (2) and 1‐octene (3) was studied using Tc2(CO)10 and Tc(CO)10/P(n‐C4H9)3, resp., as catalysts in solution. For comparison experiments have also been made with Mn2(CO)10, Mn2(CO)10/P(n‐C4H9)3 and Re2(CO)10/P(n‐C4H9)3 as catalysts for the hydroformylation of 1.There is always a competition between hydrogenation and hydroformylation.Tc2(CO)10/P(n‐C4H9)3 gave the best results in activity and selectivity within the subgroup VII complexes studied, but is a rather poor catalyst compared with the cobalt or rhodium compounds.
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