Abstract

In this study we investigate the influence of the operation method in Kelvin probe force microscopy (KPFM) on the measured potential distribution. KPFM is widely used to map the nanoscale potential distribution in operating devices, e.g., in thin film transistors or on cross sections of functional solar cells. Quantitative surface potential measurements are crucial for understanding the operation principles of functional nanostructures in these electronic devices. Nevertheless, KPFM is prone to certain imaging artifacts, such as crosstalk from topography or stray electric fields. Here, we compare different amplitude modulation (AM) and frequency modulation (FM) KPFM methods on a reference structure consisting of an interdigitated electrode array. This structure mimics the sample geometry in device measurements, e.g., on thin film transistors or on solar cell cross sections. In particular, we investigate how quantitative different KPFM methods can measure a predefined externally applied voltage difference between the electrodes. We found that generally, FM-KPFM methods provide more quantitative results that are less affected by the presence of stray electric fields compared to AM-KPFM methods.

Highlights

  • In this study, we compare the most commonly used amplitude modulation (AM) and frequency modulation (FM) Kelvin probe force microscopy (KPFM) methods under ambient conditions to investigate how these methods can measure quantitative variations in the local contact potential difference (CPD)

  • We refer to this mode as AM-KPFM second eigenmode (AM 2 EM), where the topography is measured at the first, and the CPD is measured on the second eigenmode

  • Our results show that generally, FM-KPFM methods provide more quantitative and reliable results

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Summary

Introduction

We compare the most commonly used amplitude modulation (AM) and frequency modulation (FM) Kelvin probe force microscopy (KPFM) methods under ambient conditions to investigate how these methods can measure quantitative variations in the local contact potential difference (CPD). To understand and improve the charge carrier generation and extraction within a solar cell, the local potential distribution needs to be correlated to the constituent layers of the cell. KPFM measurements have frequently been used to image potential distributions on cross sections of a range of different solar cell devices, including organic [3,4,5], and inorganic [6] as well as hybrid perovskite solar cells [7,8,9,10,11,12,13,14,15]

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