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Abstract
Kinetic investigation of the reaction of electrochemically generated\(0_2 ^{\mathop - \limits_ \bullet } \) with perfluorooctene, styrene, and cyclohexene in acetonitrile, in the presence of tetraethylammonium perchlorate used as a background electrolyte, revealed that\(0_2 ^{\mathop - \limits_ \bullet } \) reacts with styrene and perfluorooctene at the double bond, and the reactivity of the olefins with respect to\(0_2 ^{\mathop - \limits_ \bullet } \) decreases with decrease in the electrophilicity of the substituents at the double bond: perfluorooctene > styrene > cyclohexene. The main transformation products of styrene are phthalic and benzoic acid esters.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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