Abstract
Kinetics of relatively faster oxidation of thioacetamide (TA), dithiooxamide (DTO) and thiourea (TA) by peroxomonosul fate (PMS) has been studied spectrophotometrically under pseudo order condition by keeping oxidant in excess. Under these conditions, the sulfur(-II) compounds are oxidized to corresponding S-dioxides. The kinetics rate law for the oxidation of TA and TU both is eq. (A) and for the oxidation of DTO is eq. (B). d(S(- II )) kK (PMS) (S(- II ))
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