Abstract
Due to high in desulfurization activity, big in sulfur capacity and easy in regeneration, iron oxide desulfurization sorbents have been used to remove hydrogen sulfide derived from coal gas at normal temperature. At the same time the removing H2S from coal gas containing CO can generate COS, which is more difficult to removal than H2S. γ-FeOOH desulfurization sorbent was prepared by the fast oxidizing method. Kinetics study of COS formation in γ-FeOOH desulfurization was performed under 40-80°C，the CO+H2S+N2mixtures and over a residence time of 0.04~0.09s. LevenbergMarquardt and lsqcurvefit methods in MATLAB are used for the regression of experimental data. The established kinetics model of COS formation is described by the following: rCOS=8.9990*104exp(-22540/RT)PCOPH2S. The recognition of mechanism model reveals that Langmuir-Hinshelwood mechanism can perfectly fit with this reaction system.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
