Abstract
The kinetics of interaction of H 2O 2 with K[Ru(H-EDTA)Cl] at pH = 3.0, μ = 0.1 M (NaClO 4) was studied using stopped-flow spectrophotometry. The formation of the μ-peroxo complex was investigated at λ max = 390 nm. The reaction was found to be first order with respect to the metal complex and hydrogen peroxide concentrations. The activation parameters were computed and a mechanism is proposed for the formation of the μ-peroxo complex.
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