Abstract
The main problem with kinetic measurements in cyclic voltammetry is connected with the increase or the ohmic drop IR S , where R S is the uncompensated solution resistance, as the sweep rate increases. Although modern potentiostats allow some compensation or R S , total compensation is not possible. The presence or the uncompensated resistance causes nonlinearity or the potential sweep and leads to an increase in the separation or peak potentials, which may result in erroneous kinetic parameters. The development or ultramicroelectrodes has increased the possibilities or cyclic voltammetry at high sweep rates
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
