Abstract
Dependence of the reaction rate on the hydrogen partial pressure 400–150 hPa, was noted in the disproportionate of N-arylhydroxylamines in the presence of a platinum catalyst in a hydrogen-nitrogen atmosphere. This dependence is attributed to the increase in the amount of oxygen-containing products, which are strongly adsorbed on the catalyst and inhibit the reaction. At hydrogen pressures above 0.1 MPa, oxygen-containing products are not formed and the rate of disproportionation is not dependent on the hydrogen pressure.
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More From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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