Abstract

Throughout the text, the subscripts V , p , and T denote the isochronous, isobaric, or isothermal conditions, and the subscripts cr, l, or g denote the crystalline, liquid, or glassy states. If the crystallization was suppressed (for example, by rapid cooling of the liquid below its melting temperature, T m), a still equilibrium but metastable undercooled liquid state (ULS, subscripted as ULS) characterized by an excess Gibbs free enthalpy G exc(T) = G ULS-cr(T) = G ULS(T) − G cr(T) and the liquid-like temperature dependence of G ULS(T) is obtained below T m (i.e., its heat capacity is C p,ULS ∼ C p,l).KeywordsDifferential Scanning CalorimetryMetallic GlassStructural RelaxationChalcogenide GlassGlass Transition PhenomenonThese keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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