Abstract
AbstractKinetic studies were carried out on the reaction between ethylenediamine and dimeric fatty acids in melt phase. The reaction was performed at 124, 130, 145, 160, 174, and 190°C and followed by determining the acid value of the product. The polyamidation reaction was found to be of overall second order with an activation energy of 18.2 kcal/g mol up to 90% conversion and of overall third order with an activation energy of 16.4 kcal/g mol above 90% conversion.
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