Abstract

1. The study of radiation postpolymerization of butyl acrylate in the presence of cobalt porphyrin showed that the aftereffect is related to decomposition of the cobalt porphyrin-macroradical adduct formed in the starting stages of polymerization. 2. The kinetic mechanisms could be explained by assuming that chain breaking primarily takes place according to the reaction of the macroradical with the RCoP adduct.

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